A stoppage time header by fullback Lucas Vazquez earned 10-man Real Madrid a 1-0 victory at lowly Alaves.
For Mourinho, it was an emotional night at the Estadio da Luz, capped by an extraordinary 98th-minute header from Trubin that ensured Benfica snatched a last-16 spot on goal difference.
Barcelona's Robert Lewandowski scored a quick-fire second-half double to set the leaders on course for a thrashing of Real Madrid.
Vinicius Jr came off the bench to score once and set up another goal to steer champions Real Madrid to a 4-1 fightback victory over Espanyol.
Images from Sunday's action in LaLiga and Serie A.
Barcelona defeated Celta Vigo 1-0 in LaLiga, but the victory was overshadowed by an injury to Lamine Yamal.
Second-half strikes by Federico Valverde, Brahim Diaz and Endrick gave feeble Real Madrid an unconvincing 3-0 win over lowly Real Valladolid.
Real Madrid strike late to beat Dortmund and win 15th UEFA Champions League
Real Madrid have avoided defeat in their last 41 LaLiga games, the second best streak by a team in the competition's history.
Barcelona's Raphinha will miss the Champions League quarter-final against Atletico Madrid due to a hamstring injury sustained while playing for Brazil. The estimated recovery time is five weeks.
A summary of the concluding day's action in the German Cup, French Cup and La Liga.
Chelsea manager Liam Rosenior has dropped Enzo Fernandez for two matches after the midfielder publicly cast doubt over his future at Stamford Bridge.
Federico Valverde scores a hat-trick as Real Madrid defeats Manchester City 3-0 in the first leg of their Champions League last-16 tie.
Karim Benzema will leave Real Madrid as a free agent in the close season after 14 trophy-laden years
Holders Manchester City cruised into the Champions League quarter-finals for the seventh consecutive season with a 3-1 victory over FC Copenhagen.
Girona thrash Osasuna for first win of the season
Bundesliga leaders Bayern Munich powered past third-placed Eintracht Frankfurt 4-0 with an impressive display of high-pressing football on Sunday.
Marco Asensio and Vinicius Jr. scored second-half goals to earn Real Madrid a solid 2-0 win over struggling Valencia.
IMAGES from the UEFA Champions League matches played on Wednesday.
Rayo Vallecano came from behind to beat Real Madrid 3-2 on Monday with the champions failing to reclaim top spot in the standings after two consecutive games without a win.
Karim Benzema and Vinicius Jr. scored in extra time as Real Madrid fought back to beat local rivals Atletico 3-1 and reach the Copa del Rey semi-finals.
IMAGES from the UEFA Champions League matches played on Wednesday
Casemiro backs Michael Carrick for the permanent Manchester United job after a strong run that lifted the club to third in the Premier League.
Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.
A summary of Saturday's action in the LaLiga, Serie A and Bundesliga.
West Ham's Zouma given 180 hours of community service for kicking his cat
Barcelona prepares to face Newcastle in the Champions League round of 16, with coach Hansi Flick emphasising the importance of the match. The team aims to improve on last season's semi-final exit and secure their first Champions League title since 2015.
A summary of Wednesday's action in the UEFA Champions League Knock-out phase play-offs.
La Liga leaders Real Madrid were held to a frustrating 1-1 draw at lowly city rivals Rayo Vallecano on Sunday as Joselu's early strike was cancelled out by Raul de Tomas' penalty, a result that could spice up the title race with surprise package Girona.
Raphinha hat-trick fires Barcelona past Sevilla at top
Brazil defender Cicinho was officially unveiled as a Real Madrid player on Thursday
Lamine Yamal's second-half goal secured a 1-0 victory for Barcelona against Athletic Bilbao, extending their lead in La Liga.
Real Madrid manager Carlo Ancelotti said on Saturday he is happy with how new signing Kylian Mbappe is settling into life with the Spanish soccer giants and he has no concerns about his team's slow start to the LaLiga season.
Real Madrid's Jude Bellingham again proved the match-winner as he struck in added time to snatch a 2-1 victory over Getafe as the Spanish giants made their home debut in La Liga this season.
Real Madrid fought back from two goals down as Vinicius Jr grabbed a hat-trick in a thrilling 5-2 win over visitors Borussia Dortmund in the Champions League.
Zinedine Zidane has stepped down as Real Madrid coach with immediate effect five days after his team were pipped to the La Liga title by city rivals Atletico Madrid, the Spanish club said on Thursday.
Champions Real Madrid earned a 2-0 win in a feisty LaLiga encounter at Athletic Bilbao on Sunday to ensure they stayed in the hunt for the LaLiga title with leaders Barcelona.
"The result of the first leg, in this aspect, puts us a little in doubt. We will try to go all in out there from the first minute, but we have more questions and responsibility than our rival."
Vinicius Jr scored a hat-trick in the first half as Real Madrid were crowned Spanish Super Cup champions
'OK. RM was not happy we were celebrating KDB goal,' Haaland, whose son has scored 51 goals for city in his first season in England, said on Twitter.
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